• Cast: Robert Hays (Tony Stark / Iron Man), James Avery (Jim Rhodes / War Machine / Whirlwind), Ed Gilbert (The Mandarin), Jim Cummings (Modok), Tony Steedman (Justin Hammer), Casey De Franco (Julia Carpenter / Spider Woman), Katherine Moffat (Wanda Frank / Scarlet Witch), James Warwick (Century), John Reilly (Hawkeye), Linda Holdahl (Hypnotia), Neil Dickson (Dreadknight), Chuck McCann (Blizzard), Jeannie Elias (Veronica Benning)
• Written By: Ron Friedman
• Note: Each episode of Season one started with a live action segment in which Stan Lee introduced the episode. These introductions were removed from later syndication packages and are not on the DVDs.

• Cast: Robert Hays (Tony Stark / Iron Man / Charter Boat Captain), James Avery (Jim Rhodes / War Machine), Ed Gilbert (The Mandarin / Ultimo), Jim Cummings (Modok / Luciano Pavarotti), Tony Steedman (Justin Hammer), James Warwick (Century / Sam Jaggers), John Reilly (Clint / Hawkeye / Vacationing Man), Casey De Franco (Julia Carpenter / Spider Woman / Shepherd Girl / Vacationing Woman), Katherine Moffat (Wanda Frank / Scarlet Witch)
• Story By: Ron Friedman
• Teleplay By: Ted Pedersen & Francis Moss

• Cast: Robert Hays (Tony Stark / Iron Man), James Avery (Jim Rhodes / War Machine), Ed Gilbert (The Mandarin), Jim Cummings (Modok / E.L.F. / President Clinton), Tony Steedman (Justin Hammer), James Warwick (Century), John Reilly (Hawkeye), Casey De Franco (Julia Carpenter / Spider Woman), Katherine Moffat (Wanda Frank / Scarlet Witch), Neil Ross (Anchorman), J.C. Lee (Computer Voice)
• Story By: Stan Lee & Ron Friedman
• Teleplay By: Douglas Booth

• Cast: Robert Hays (Tony Stark / Iron Man), James Avery (Jim Rhodes / War Machine / Whirlwind / Blacklash), Ed Gilbert (The Mandarin), Jim Cummings (Modok / General Quirt), Tony Steedman (Justin Hammer), Casey De Franco (Julia Carpenter / Spider Woman), Katherine Moffat (Wanda Frank / Scarlet Witch / Rachel Carpenter), James Warwick (Century), Neil Dickson (Dreadknight), Chuck McCann (Blizzard), Marla Rubinoff (Consuela / Leslie)
• Story By: Ron Friedman
• Teleplay By: Steve Hayes

• Cast: Robert Hays (Tony Stark / Iron Man), James Avery (Jim Rhodes / War Machine / Whirlwind / Blacklash), Ed Gilbert (The Mandarin / Gray Gargoyle), Jim Cummings (Modok), Tony Steedman (Justin Hammer), Casey De Franco (Julia Carpenter / Spider Woman), Katherine Moffat (Wanda Frank / Scarlet Witch), James Warwick (Century), John Reilly (Hawkeye), Chuck McCann (Blizzard), Jeannie Elias (Veronica Benning)
• Story By: Stan Lee & Ron Friedman
• Teleplay By: Douglas Booth

• Cast: Robert Hays (Tony Stark / Iron Man), James Avery (Jim Rhodes / War Machine / Whirlwind / Blacklash), Ed Gilbert (The Mandarin / Gray Gargoyle), Jim Cummings (Modok / Robot Captain / Robot Sentries), James Warwick (Century / Sam Jaggers), John Reilly (Clint / Hawkeye), Casey De Franco (Julia Carpenter / Spider Woman), Katherine Moffat (Wanda Frank / Scarlet Witch), Chuck McCann (Blizzard / Camera Man), Neil Dickson (Dreadknight / Henry), Linda Holdahl (Hypnotia / Computer Voice), Sarah Douglas (Alana Ulanova)
• Written By: Ron Friedman

• Cast: Robert Hays (Tony Stark / Iron Man), James Avery (Jim Rhodes / War Machine / Whirlwind / Blacklash), Ed Gilbert (The Mandarin / Brock), Jim Cummings (Modok), James Warwick (Century), John Reilly (Clint / Hawkeye), Casey De Franco (Julia Carpenter / Spider Woman), Katherine Moffat (Wanda Frank / Scarlet Witch / Armor Computer Voice), Tony Steedman (Justin Hammer), Chuck McCann (Blizzard), Neil Dickson (Dreadknight), Neil Ross (Fin Fang Foom / Yinsen), Linda Holdahl (Hypnotia), Marla Rubinoff (Ilona / Hall Computer Voice)
• Written By: Ron Friedman

• Cast: Robert Hays (Tony Stark / Iron Man), Dorian Harewood (Jim / War Machine / Blacklash), Ed Gilbert (The Mandarin / Gargoyle), Jim Cummings (Modok / Old Man), James Warwick (Century), John Reilly (Clint / Hawkeye), Casey De Franco (Julia Carpenter / Spider Woman), Katherine Moffat (Wanda Frank / Scarlet Witch / Armor Computer Voice), Tony Steedman (Justin Hammer), James Avery (Whirlwind), Chuck McCann (Blizzard), Neil Dickson (Dreadknight), Linda Holdahl (Hypnotia)
• Written By: Ron Friedman

• Cast: Robert Hays (Tony Stark / Iron Man / Duplicate Iron Man), James Avery (Jim Rhodes / War Machine / Whirlwind / Blacklash), Ed Gilbert (The Mandarin / Vice President Gore), Jim Cummings (Modok / President Clinton), James Warwick (Century / Sam Jaggers), John Reilly (Clint / Hawkeye / Nkrumah), Casey De Franco (Julia Carpenter / Spider Woman), Katherine Moffat (Wanda Frank / Scarlet Witch), Neil Dickson (Dreadknight / Hammer Guard), Linda Holdahl (Hypnotia), Chuck McCann (Blizzard), Tony Steedman (Justin Hammer)
• Story By: Ron Friedman
• Teleplay By: Yale Yudoff

• Cast: Robert Hays (Tony Stark / Iron Man / Duplicate Iron Man / Living Laser), Dorian Harewood (Jim Rhodes / War Machine / Whirlwind / Blacklash), Ed Gilbert (The Mandarin / Grey Gargoyle / Cop), Jim Cummings (Modok / Narrator), James Warwick (Century), John Reilly (Clint / Hawkeye), Katherine Moffat (Wanda Frank / Scarlet Witch / Starlet), Casey De Franco (Julia Carpenter / Spider Woman / Old Woman), Neil Dickson (Dreadknight), Linda Holdahl (Hypnotia / Hall Computer Voice / Helicopter Voice), Tony Steedman (Justin Hammer), Chuck McCann (Blizzard), Ron Friedman (Record Producer)
• Written By: Ron Friedman & Yale Yudoff

• Cast: Robert Hays (Tony Stark / Iron Man / Living Laser / Tony - All Ages), Dorian Harewood (Jim Rhodes / War Machine), Ed Gilbert (The Mandarin), Jim Cummings (Modok), James Warwick (Century / General Hirsch), John Reilly (Clint / Hawkeye / Irving), Casey De Franco (Julia Carpenter / Spider Woman), Katherine Moffat (Wanda Frank / Scarlet Witch), Neil Dickson (Dreadknight / Foreman), Linda Holdahl (Hypnotia), Dimitra Arlys (Armor Computer Voice / Tony's Mother), Neil Ross (Fin Fang Foom / Tony's Father / Yinsen)
• Written By: Ron Friedman

• Cast: Robert Hays (Tony Stark / Iron Man), Dorian Harewood (Jim Rhodes / War Machine / Whirlwind / Blacklash), Ed Gilbert (The Mandarin), Jim Cummings (Modok), James Warwick (Century), John Reilly (Clint / Hawkeye / Irving), Katherine Moffat (Wanda Frank / Scarlet Witch), Casey De Franco (Julia Carpenter / Spider Woman), Neil Dickson (Dreadknight), Linda Holdahl (Hypnotia), Chuck McCann (Blizzard), Tony Steedman (Justin Hammer), Neil Ross (Fin Fang Foom / Yinsen), Dimitra Arlys (Computer Voice)
• Written By: Ron Friedman

• Cast: Robert Hays (Tony Stark / Iron Man / Living Laser), Dorian Harewood (Jim Rhodes / War Machine / Whirlwind / Blacklash), Ed Gilbert (The Mandarin), Jim Cummings (Modok / The Minister), James Warwick (Century / Sam Jaggers), John Reilly (Clint / Hawkeye), Katherine Moffat (Wanda Frank / Scarlet Witch), Casey De Franco (Julia Carpenter / Spider Woman), Neil Dickson (Dreadknight), Linda Holdahl (Hypnotia / Armor Computer / Car Computer), Tony Steedman (Justin Hammer), Chuck McCann (Blizzard)
• Written By: Ron Friedman